Bromobenzene CAS#108-86-1

CAS Number: 108-86-1
Chemical Formula: C6H5Br
Synonyms:

MONOBROMOBENZENE
1-Bromobenzene
Benzene,bromo-

Appearance: Yellow Liquid

MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)

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Bromobenzene CAS#108-86-1

Bromobenzene is a flammable, clear, colorlessmobile liquid with a pleasant odor. Molecularweight=157.02. Specific gravity (H2O:1)=1.48; Boilingpoint=156℃; Freezing/Melting point=2 31℃; Flashpoint=51℃; Autoignition temperature=565℃. Explosivelimits in air: LEL=6%; UEL=36.5%[icsc]. HazardIdentification (based on NFPA-704 M Rating System):Health 2, Flammability 2, Reactivity 0. Very slightly soluble in water; solubility=0.04% at 25℃.

Bromobenzene Chemical Properties

Melting point	-31 °C
Boiling point	156 °C(lit.)
density	1.491 g/mL at 25 °C(lit.)
vapor density	5.41 (vs air)
vapor pressure	10 mm Hg ( 40 °C)
refractive index	n20/D 1.559(lit.)
Fp	124 °F
storage temp.	Store below +30°C.
solubility	Miscible with diethyl ether, alcohol, carbon tetrachloride, chloroform and benzene.
form	Liquid
color	Clear colorless to faintly yellow
Odor	pleasant smell
explosive limit	0.5-2.5%(V)
Water Solubility	insoluble. <0.1 g/100 mL at 20.5 ºC
Merck	14,1406
BRN	1236661
Henry's Law Constant	2.47 at 25 °C (gas stripping-GC, Shiu and Mackay, 1997)
Dielectric constant	5.4（20℃）
Stability:	Stable. Combustible. Incompatible with strong oxidizing agents.
InChI	1S/C6H5Br/c7-6-4-2-1-3-5-6/h1-5H
InChIKey	QARVLSVVCXYDNA-UHFFFAOYSA-N
SMILES	Brc1ccccc1
LogP	3.14 at 25℃
Surface tension	33.5mN/m at 303.15K
CAS DataBase Reference	108-86-1(CAS DataBase Reference)
NIST Chemistry Reference	Benzene, bromo-(108-86-1)
EPA Substance Registry System	Bromobenzene (108-86-1)

Safety Information

Hazard Codes	Xi,N,F,T
Risk Statements	10-38-51/53-39/23/24/25-23/24/25
Safety Statements	61-45-36/37
RIDADR	UN 2514 3/PG 3
WGK Germany	2
RTECS	CY9000000
Autoignition Temperature	565 °C
TSCA	TSCA listed
HS Code	2903 99 80
HazardClass	3
PackingGroup	III
Storage Class	3 - Flammable liquids
Hazard Classifications	Aquatic Chronic 2 Flam. Liq. 3 Skin Irrit. 2
Hazardous Substances Data	108-86-1(Hazardous Substances Data)
Toxicity	LD50 orally in Rabbit: 2383 mg/kg

Product Application of Bromobenzene CAS#108-86-1

The compound is employed as a starting material in organic syntheses in which a Grignard intermediate (phenyl magnesium bromide) is used. The material is a chemical precursor for certain agricultural products and has been used as an additive to motor oils. Bromobenzene has also been used as a high-density solvent for chemical recrystallization processes. especially for crystallizations on a large scale and where a heavy liquid is desirable.

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